Activity of Nitrogen Containing Carbon Nanotubes in Base Catalyzed Knoevenagel Condensation

Base-free Knoevenagel condensation catalyzed by copper metal surfaces.

For the first time Knoevenagel condensation has been catalyzed by elemental copper with unexpected activity and excellent isolated yields. Inexpensive, widely available copper powder was used to catalyze the condensation of cyanoacetate and benzaldehyde under mild conditions. To ensure general applicability, a wide variety of different substrates was successfully reacted.

Nitrogen-containing carbon nanotubes as solid base catalysts.

Nitrogen-containing carbon nanotubes (NCNT) are effective re-usable solid base catalysts, their activity for a Knoevenagel condensation being related to the amount of pyridinic nitrogen incorporated in the NCNT structure, which could be tuned by the synthesis parameters of the catalyst.

Nitrogen-Containing Carbon Nanotubes - A Theoretical Approach

MATERIALS CHEMISTRY COMMUNICATION Nitrogen-containing carbon nanotubes

could be prepared by employing appropriate precursor molecules. Nanotubes containing both boron and nitrogen have Carbon nanotubes containing small amounts of nitrogen are been grown in the electric arc discharge between graphite produced by the pyrolysis of aza-aromatics such as pyridine, cathodes and graphite anodes filled with boron in a nitrogen methylpyrimidine and triazine over cobalt nan...

First-principles calculations for nitrogen-containing single-walled carbon nanotubes

We present calculations for possible configurations of nitrogen-containing single-walled carbon nanotubes and their electronic properties obtained with the ab initio tight-binding FIREBALL method. It is found that nitrogen atoms can be energetically incorporated into the carbon network in three forms: Substitution, substitution with formation of a vacancy structure, and chemical adsorption. The...